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Organotin compounds, used as antifouling biocides since 1960, are chemical compounds that act as endocrine disrupters. It is not known how organotin compounds cause hormone disturbance, however, and many questions remain about their effect on aquatic organisms. Studies on organotin compounds have recently evolved, with many new findings reported. Following a worldwide ban on organotin compounds in 2008, alternative compounds will mainly be used, with the potential for coastal areas to become contaminated, causing, among other effects, cholinesterase inhibition in aquatic organisms. Use of alternative compounds must be controlled to avoid such errors. These and other findings are described and concisely summarized in this book, providing a useful reference in countries where alternative biocides are being considered. Included are studies on the effects on marine organisms, making this book an excellent aid to experts in environmental chemistry, to government organizations, and to students.

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This digital document is a journal article from Environmental Pollution, published by Elsevier in 2004. The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.

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An increasing number of vegetable-based oils are being developed as environmentally friendly alternatives to petroleum products. However, toxicity towards key tropical marine species has not been investigated. In this study we used laboratory-based biomarker induction experiments to compare the relative stress of a vegetable-based lubricating oil for marine 2-stroke engines with its mineral oil-based counterpart on tropical fish. The sub-lethal stress of 2-stoke outboard lubricating oils towards the fish Lates calcarifer (barramundi) was examined using liver microsomal mixed function oxidase (MFO) induction assays. This study is the first investigation into the use of this key commercial species in tropical North Queensland, Australia in stress assessment of potential hydrocarbon pollution using ethoxyresorufin O-deethylase (EROD) induction. Our results indicated that barramundi provide a wide range of inducible rates of EROD activity in response to relevant organic stressors. The vegetable- and mineral-based lubricants induced significant EROD activity at 1.0 mg kg^-^1 and there was no significant difference between the two oil treatments at that concentration. At increasing concentrations of 2 and 3 mg kg^-^1, the mineral-based lubricant resulted in slightly higher EROD activity than the vegetable-based lubricant. The EROD activity of control and treated barramundi are found to be within ranges for other species from temperate and tropical environments. These results indicate that vegetable-based lubricants may be less stressful to barramundi than their mineral counterparts at concentrations of lubricant >=2 mg kg^-^1. There is great potential for this species to be used in the biomonitoring of waterways around tropical North Queensland and SE Asia. ... Read more

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This digital document is a journal article from Environmental Pollution, published by Elsevier in 2004. The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.

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Biodegradable vegetable-derived lubricants (VDL) might be less toxic to marine organisms than mineral-derived oils (MDL) due to the absence of high molecular weight aromatics, but this remains largely untested. In this laboratory study, adult corals and coral gametes were exposed to various concentrations of a two-stroke VDL-1A and a corresponding MDL to determine which lubricant type was more toxic to each life stage. In the fertilization experiment, gametes from the scleractinian coral Acropora microphthalma were exposed to water-accommodated fractions (WAF) of VDL-1A and MDL for four hours. The MDL and VDL-1A WAFs inhibited normal fertilization of the corals at 200 @mg l^-^1 total hydrocarbon content (THC) and 150 @mg l^-^1 THC respectively. Disturbance of a stable coral-dinoflagellate symbiosis is regarded as a valid measure of sub-lethal stress in adult corals. The state of the symbiosis in branchlets of adult colonies of Acropora formosa was monitored using indicators such as dinoflagellate expulsion and dark-adapted photosystem II yields of dinoflagellate (using pulse amplitude modulation fluorescence). An effect on symbiosis was measurable following 48 h exposure to the lubricants at concentrations of 190 @mg l^-^1 and 37 @mg l^-^1 THC for the MDL and VDL-1A respectively. GC/MS revealed that the main constituent of the VDL-1A WAF was the compound coumarin, added by the manufacturer to improve odour. The fragrance containing coumarin was removed from the lubricant formulation and the toxicity towards adult corals re-examined. The coumarin-free VDL-2 exhibited significantly less toxicity towards the adult corals than all of the other oil types tested, with the only measurable effect being a slight but significant drop in photosynthetic efficiency at 280 @mg l^-^1. ... Read more

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This volume is produced from digital images created through the University of Michigan University Library's large-scale digitization efforts. The Library seeks to preserve the intellectual content of items in a manner that facilitates and promotes a variety of uses. The digital reformatting process results in an electronic version of the original text that can be both accessed online and used to create new print copies. The Library also understands and values the usefulness of print and makes reprints available to the public whenever possible. This book and hundreds of thousands of others can be found in the HathiTrust, an archive of the digitized collections of many great research libraries. For access to the University of Michigan Library's digital collections, please see http://www.lib.umich.edu and for information about the HathiTrust, please visit http://www.hathitrust.org ... Read more

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This digital document is a journal article from Environmental Pollution, published by Elsevier in 2006. The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.

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Acid resins are residues produced in a recycling process for used oils that was in use in the forties and fifties of the last century. The resin-like material is highly contaminated with mineral oil hydrocarbons, extremely acidic and co-contaminated with substituted and aromatic hydrocarbons, and heavy metals. To determine the potential for microbial biodegradation the acid resin deposit and its surroundings were screened for microbial activity by soil respiration measurements. No microbial activity was found in the core deposit. However, biodegradation of hydrocarbons was possible in zones with a lower degree of contamination surrounding the deposit. An extreme acidophilic microbial community was detected close to the core deposit. With a simple ecotoxicological approach it could be shown that the pure acid resin that formed the major part of the core deposit, was toxic to the indigenous microflora due to its extremely low pH of 0-1. ... Read more

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This digital document is a journal article from Ecological Engineering, published by Elsevier in 2004. The article is delivered in HTML format and is available in your Amazon.com Media Library immediately after purchase. You can view it with any web browser.

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This digital document is an article from Environmental Health Perspectives, published by Thomson Gale on January 1, 2006. The length of the article is 7698 words. The page length shown above is based on a typical 300-word page. The article is delivered in HTML format and is available in your Amazon.com Digital Locker immediately after purchase. You can view it with any web browser.

Citation Details
Title: Recent applications of DNA microarray technology to toxicology and ecotoxicology.
Author: Teresa Lettieri
Publication: Environmental Health Perspectives (Magazine/Journal)
Date: January 1, 2006
Publisher: Thomson Gale
Volume: 114Issue: 1Page: 4(6)

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The USEPA's ambient water quality criteria (AWQC) for cyanide were developed in 1984. Recently, however, concerns have arisen that the AWQC for cyanide have been problematic to implement and may not accurately reflect either the toxic forms or bioavailable concentrations of cyanide in water, sediments, and tissues of aquatic organisms. Also, the cyanide criteria typically have been implemented based on total cyanide concentrations rather than the free cyanide concentrations that formed the basis of the criteria calculations. New knowledge on cyanide toxicity, cyanide speciation and its measurement, and the relative toxicity of bioavailable cyanide species suggested that a re-evaluation of the aquatic toxicity data and chemistry that serve as the basis of the current national criteria is warranted. In response to these concerns, studies sponsored by the Water Environment Research Foundation (WERF) evaluated the formation and fate of cyanide in municipal wastewater effluents. Kavanaugh et al.(2003) evaluated the reliability of several analytical methods for measurement of cyanide species at low (ppb) concentrations, along with studies to evaluate the sources, transport, and fate of cyanide species in wastewater treatment plants (WWTPs) and receiving waters. Results indicated that potentially toxic forms of cyanide can be generated in WWTPs from several chemical processes, including dissociation of thiocyanate by chlorination or UV disinfection, chlorination in the presence of residual ammonia, nitrosation, and photolysis of ferrocyanate. Models were developed for predicting the fate of these compounds in surface waters downstream of WWTP effluents to establish where organisms might be most at risk from cyanide exposure. While implementation of these results could assist in the development of site-specific water quality standards for cyanide, a more thorough update to the National AWQC was warranted to apply our more current scientific understanding of cyanide toxicology to the derivation of aquatic life criteria.The present study was therefore undertaken to review and update knowledge of the aquatic toxicity of cyanide, and to develop recommended updates to the existing national AWQC to enhance the scientific basis of the concentrations and chemical forms of cyanide specified for protection of aquatic organisms.This update was conducted according to USEPA guidance for derivation of AWQC for protection of aquatic life, and is based both on an extensive literature review and on new toxicity studies that fill key data gaps. This re-evaluation of cyanide criteria also includes consideration of impacts on benthic (sediment) organisms, wildlife that consume aquatic biota, and possible effects to threatened and endangered species to ensure that revised criteria are adequately protective of the entire aquatic ecosystem. ... Read more