Victor Grignard - Biography François Auguste victor grignard was born in Cherbourg on May 6 grignard shared theCahours Prize (Institut de France In 1912 the nobel Prize for Chemistry was http://www.nobel.se/chemistry/laureates/1912/grignard-bio.html
Extractions: Grignard's first investigations concerned "ethyl b -isopropylacetobutyrate and the stereoisomeric diisopropylbutenedicarboxylic acids" and studies of branched unsaturated hydrocarbons. In 1899, on Barbier's recommendation, he studied organomagnesium compounds and his discovery of the classic preparation of magnesium alkyl halides was first communicated by Henri Moissan Grignard was the author of some 170 publications on his researches and, at his death, he was working to fulfil his ambition to see a great chemical reference work in the French language. Two volumes of his (Treatise on organic chemistry) had already been published, two more were ready for the press and the editorial work for another two was well advanced: it was later to be finished by his collaborators. In 1937, two of his students, Jean Cologne and Roger Grignard, published (Survey of organic chemistry) which is based on Grignard's lecture course in organic chemistry.
Chemistry 1912 The nobel Prize in Chemistry 1912. for the years . victor grignard,Paul Sabatier. 1/2 of the prize, 1/2 of the prize. France, France. Nancy http://www.nobel.se/chemistry/laureates/1912/
Extractions: "for the discovery of the so-called Grignard reagent, which in recent years has greatly advanced the progress of organic chemistry" "for his method of hydrogenating organic compounds in the presence of finely disintegrated metals whereby the progress of organic chemistry has been greatly advanced in recent years" Victor Grignard Paul Sabatier 1/2 of the prize 1/2 of the prize France France Nancy University
Index Of Nobel Laureates In Chemistry ALPHABETICAL LISTING OF nobel PRIZE LAUREATES IN CHEMISTRY. Name, Year Awarded.Alder, Kurt, 1950. Gilbert, Walter, 1980. grignard, victor, 1912. Haber, Fritz,1918. http://almaz.com/nobel/chemistry/alpha.html
Victor Grignard Francois Auguste victor grignard. French chemist, nobel Prizewinner in 1912 forgrignard reagents Born Cherbourg, 6 May 1871 Died Lyon, 13 December, 1935. http://www.sunderland.ac.uk/~hs0bcl/h_vg.htm
Extractions: Died: Lyon, 13 December, 1935 Victor Grignard had a strange start in academic life for a chemist - he took a maths degree. When he eventually switched to chemistry, it wasn't to the mathematical province of physical chemistry but to organic chemistry. While attempting to find an efficient catalyst for the process of methylation, he noted that Zn in diethyl ether had been used for this purpose and wondered whether the Mg/ether combination might be successful. Grignard reagents were first reported in 1900 and Grignard used this work for his doctoral thesis in 1901. In 1910, Grignard obtained a professorship at the University of Nancy and in 1912 was awarded the Nobel prize for chemistry which he shared with Paul Sabatier who had made advances in Nickel catalysed hydrogenation. History top Home Ol' Spidey : page last changed 2 June 1996
The Grignard Reaction and won him the nobel Prize in 1912. We now refer to such compounds as grignard Reagents and they are the first tool in your bag. victor's breakthrough came http://www.sunderland.ac.uk/~hs0bcl/org3.htm
Extractions: How to Tackle Organic Syntheses - a Beginner's Guide by Prof Otto Meth-Cohn The Grignard Reaction Victor Grignard was an enthusiastic young French chemist who discovered how to make organomagnesium halides (RMgX) while working for his PH.D. His boss, Barbier, had been trying this sort of chemistry for some time, but Victor was the genius who solved the problem. This discovery in 1901 changed the course of organic chemistry and won him the Nobel Prize in 1912. We now refer to such compounds as Grignard Reagents - and they are the first tool in your bag. Victor's breakthrough came with two discoveries - an ether solvent was vital and the whole chemistry must be carried out bone dry . You take an alkyl halide (preferably a bromide or iodide but a very reactive chloride such as tertiary-butyl chloride or benzyl chloride will be OK) magnesium metal and ether (dried with sodium metal) and with a little persuasion you get a vigorous reaction resulting in a Grignard reagent. The reagent is used in solution (it is soluble in ether) and is never isolated. The metal is positively polarised and the alkyl group thus is like a carbanion. It certainly behaves as a carbanion. All kinds of alkyl halides react - and amazingly, even bromobenzene and other aryl bromides and iodides react easily with magnesium. This is particularly surprising since the aromatic halogen is so unreactive. For example, it is inert to refluxing aqueous sodium hydroxide even above 200C.
Grignard, Victor AUGUSTEvictor-grignard (b. May 6, 1871, Cherbourg, Franced. Dec. 13, 1935, Lyon),French chemist and corecipient, with Paul Sabatier, of the nobel Prize for http://www.britannica.com/nobel/micro/247_60.html
Extractions: Victor Grignard, print Library of Congress/Corbis Paul Sabatier , of the Nobel Prize for Chemistry in 1912 for his development of the Grignard reaction. This work in organomagnesium compounds opened a broad area of organic synthesis. In 1898, while a student under Philippe Barbier at Lyon, Grignard began his prizewinning work with a study of the alkylzinc compounds developed earlier by Sir Edward Frankland. It was Barbier who had Grignard repeat some experiments on the preparation of a tertiary alcohol from a mixture of methyl heptyl ketone, magnesium, and methyl iodide. Grignard hit upon the idea of treating the iodide with the magnesium first and carried out the reaction in ether. This first of the Grignard reagents was a complete success. Grignard's doctoral dissertation (1901) described the preparation of alcohols, acids, and hydrocarbons by means of reactions of organomagnesium compounds. He became professor of chemistry at Nancy (1910) and at Lyon (1919). At the time of his death some 6,000 papers reporting applications of the Grignard reaction had been published.
Nobel Prize Winners For Chemistry 1911, Curie, Marie, France, discovery of radium and polonium; isolation ofradium. 1912, grignard, victor, France, discovery of the grignard reagents. http://www.britannica.com/nobel/table/chem.html
Extractions: Year Article Country* Achievement Hoff, Jacobus Henricus van't The Netherlands laws of chemical dynamics and osmotic pressure Fischer, Emil Germany work on sugar and purine syntheses Arrhenius, Svante Sweden theory of electrolytic dissociation Ramsay, Sir William U.K. discovery of inert gas elements and their places in the periodic system Baeyer, Adolf von Germany work on organic dyes, hydroaromatic compounds Moissan, Henri France isolation of fluorine; introduction of Moissan furnace Buchner, Eduard Germany discovery of noncellular fermentation Rutherford, Ernest U.K. investigations into the disintegration of elements and the chemistry of radioactive substances Ostwald, Wilhelm Germany pioneer work on catalysis, chemical equilibrium, and reaction velocities Wallach, Otto Germany pioneer work in alicyclic combinations Curie, Marie France discovery of radium and polonium; isolation of radium Grignard, Victor France discovery of the Grignard reagents Sabatier, Paul France method of hydrogenating organic compounds Werner, Alfred
Extractions: Select Search All Bartleby.com All Reference Columbia Encyclopedia World History Encyclopedia World Factbook Columbia Gazetteer American Heritage Coll. Dictionary Roget's Thesauri Roget's II: Thesaurus Roget's Int'l Thesaurus Quotations Bartlett's Quotations Columbia Quotations Simpson's Quotations English Usage Modern Usage American English Fowler's King's English Strunk's Style Mencken's Language Cambridge History The King James Bible Oxford Shakespeare Gray's Anatomy Farmer's Cookbook Post's Etiquette Bulfinch's Mythology Frazer's Golden Bough All Verse Anthologies Dickinson, E. Eliot, T.S. Frost, R. Hopkins, G.M. Keats, J. Lawrence, D.H. Masters, E.L. Sandburg, C. Sassoon, S. Whitman, W. Wordsworth, W. Yeats, W.B. All Nonfiction Harvard Classics American Essays Einstein's Relativity Grant, U.S. Roosevelt, T. Wells's History Presidential Inaugurals All Fiction Shelf of Fiction Ghost Stories Short Stories Shaw, G.B. Stein, G. Stevenson, R.L. Wells, H.G. Reference Columbia Encyclopedia PREVIOUS NEXT ... BIBLIOGRAPHIC RECORD The Columbia Encyclopedia, Sixth Edition. Grignard, Victor
Extractions: Select Search All Bartleby.com All Reference Columbia Encyclopedia World History Encyclopedia World Factbook Columbia Gazetteer American Heritage Coll. Dictionary Roget's Thesauri Roget's II: Thesaurus Roget's Int'l Thesaurus Quotations Bartlett's Quotations Columbia Quotations Simpson's Quotations English Usage Modern Usage American English Fowler's King's English Strunk's Style Mencken's Language Cambridge History The King James Bible Oxford Shakespeare Gray's Anatomy Farmer's Cookbook Post's Etiquette Bulfinch's Mythology Frazer's Golden Bough All Verse Anthologies Dickinson, E. Eliot, T.S. Frost, R. Hopkins, G.M. Keats, J. Lawrence, D.H. Masters, E.L. Sandburg, C. Sassoon, S. Whitman, W. Wordsworth, W. Yeats, W.B. All Nonfiction Harvard Classics American Essays Einstein's Relativity Grant, U.S. Roosevelt, T. Wells's History Presidential Inaugurals All Fiction Shelf of Fiction Ghost Stories Short Stories Shaw, G.B. Stein, G. Stevenson, R.L. Wells, H.G. Reference American Heritage Dictionary grig ... BIBLIOGRAPHIC RECORD The American Heritage Dictionary of the English Language: Fourth Edition. SYLLABICATION: PRONUNCIATION gr DATES: French chemist. He shared a 1912 Nobel Prize for his discovery of a group of reagents used in the synthesis of organic compounds.
Grignard, Victor grignard, victor , 18711935, French chemist. He shared the 1912 nobel Prize inChemistry for his work in organic synthesis based on his discovery (1900) of http://www.infoplease.com/cgi-bin/id/A0821860
Grignard Reagent nitrogen. grignard reagents are named after victor grignard, a Frenchchemist, who received a nobel Prize (1912) for their discovery. http://www.infoplease.com/ce6/sci/A0821861.html
Extractions: Pronunciation Key Grignard reagent , any of an important class of extremely reactive chemical compounds used in the synthesis of hydrocarbons, alcohols, carboxylic acids, and other compounds. Chemically, a Grignard reagent is an organic magnesium halide dissolved in a nonreactive solvent (typically dry ethyl ether). The substance is made up of an organic group, e.g., an alkyl or aryl group, joined by a highly polar covalent bond (see chemical bond ) to magnesium, while the magnesium is joined by an ionic bond to a halogen ion, e.g., bromide or iodide. A Grignard reagent will react with water, oxygen, carbon dioxide, or almost any electrophilic organic compound. The reaction of Grignard reagents with aldehydes to form alcohols is of particular importance in the laboratory. Because Grignard reagents are so unstable, they are generally prepared just before use by reacting an organic halide, e.g., methyl iodide, with magnesium metal in a completely dry solvent; air is usually excluded from the reaction vessel, e.g., by flushing it with nitrogen. Grignard reagents are named after Victor
Victor Grignard (1871 - 1935) Translate this page carboxyliques Pour cette découverte, victor grignard partagea en 1912le prix nobel de chimie avec le chimiste français Paul Sabatier. http://isimabomba.free.fr/biographies/chimistes/grignard.htm
GRIGNARD VICTOR (1871-1935) Translate this page victor grignard fut un chimiste français, né à Cherbourg et de composés organomagnésiens(réactifs de grignard) sur les il reçu le prix nobel de chimie http://histoirechimie.free.fr/Lien/GRIGNARD.htm
Prix Nobel De Chimie Translate this page de Chimie Prix nobel, 1901 JH Van't Hoff (NL). 1912. victor grignard (1871-1935)a été récompensé pour la découverte du réactif de grignard. http://histoirechimie.free.fr/Nobel.htm
Extractions: J.H. Van't Hoff (NL) E. Fischer (D) S. Arrhenius (S) W. Ramsay (GB) A. Von Baeyer (D) H. Moissan (F) E. Buchner (D) E. Rutherford (GB) W. Ostwald (D) O. Wallach (D) M.Curie (F) V. Grignard (F) et P. Sabatier (F) A.Werner (CH) Th. Richards (USA) R. Willstatter (D) F. Haber (D) W. Nernst (D) F. Soddy (GB) F. W. Aston (GB) F. Pregl (A) R. Zsigmondy (D) T Svedberg (S) H. Wieland (D) A. Windaus (D) A. Harden (GB) et H. Von Euler-Chelpin (D) H. Fischer (D) C.Bosch (D) et F. Bergius (D) J. Langmuir (USA) H.C. Urey (USA) J. F. Joliot-Curie (F) et I. Joliot-Curie (F) P Debye (NL) W.N. Haworth (GB) et P. Karrer (CH) A.F.J. Butenandt (D) et L. Ruzicka (CH) G. de Hevesy (S) O. Hahn (D) A.J. Virtanen (SF) J.B. Sumner (USA), J.H. Northrop (USA) et W.M. Stanley (USA) R. Robinson (GB) A.W.K. Tiselius (S) W.E Giauque (USA) O. Diels (D) et K. Alder (D) G.T.Seaborg (USA) et E.M. Mac Millan (USA) A.J.P. Martin (GB) et L.M. Synge (GB) H. Staudinger (D) L. Pauling (USA) V. du Vigneaud (USA) A. Todd (GB)
Nobel Prizes In Chemistry nobel Prizes in Chemistry. This Year's nobel Prize in Chemistry Chemistry1901. grignard, victor, France, Nancy University, * 1871, + 1935 http://www.bc.edu/bc_org/avp/cas/chem/acs-inorganic/Nobel.html
Extractions: This Year's Nobel Prize in Chemistry VAN'T HOFF, JACOBUS HENRICUS, the Netherlands, Berlin University, Germany, * 1852, + 1911: "in recognition of the extraordinary services he has rendered by the discovery of the laws of chemical dynamics and osmotic pressure in solutions". FISCHER, HERMANN EMIL, Germany, Berlin University, * 1852, + 1919 "in recognition of the extraordinary services he has rendered by his work on sugar and purine syntheses". ARRHENIUS, SVANTE AUGUST, Sweden, Stockholm University, * 1859, + 1927 "in recognition of the extraordinary services he has rendered to the advancement of chemistry by his electrolytic theory of dissociation". RAMSAY, Sir WILLIAM, Great Britain, London University, * 1852, + 1916: "in recognition of his services in the discovery of the inert gaseous elements in air, and his determination of their place in the periodic system". VON BAEYER, JOHANN FRIEDRICH WILHELM ADOLF, Germany, Munich University, * 1835, + 1917:
Francois Auguste Victor Grignard Translate this page Auguste victor grignard (1871 - 1935) Químico francês nascido em Cherbourg, professorda Universidade de Nancy (1909-1932) e um dos ganhadores do nobel de http://www.sobiografias.hpg.ig.com.br/VictorGr.html
Extractions: reagente de Grignard Louis Bouveault . Depois foi promovido depois a pesquisador com Philippe Barbier (1901), obtendo o grau de Blaise Barbier Paul Sabatier Cahours Prize do Institut de France (1901/1902) e o Prix Jecker (1912). Foi nomeado Officier (1920) e Commandeur da Universidade de Nancy (1931), das Universidades de Bruxelas e Louvain, e Honorary Fellow Augustine Marie Boulant Roger , que seguiu a carreira do pai, e morreu em Lyon.
Biographie Grignard Translate this page victor grignard. 1871-1935. victor grignard, prix nobel à 41 ans, fait partiedes grands chimistes français qui ont laissé leur nom dans l'histoire. http://chimie.scola.ac-paris.fr/sitedechimie/hist_chi/biographies/biog_grignard.
Extractions: Victor Grignard Victor Grignard, prix Nobel à 41 ans, fait partie des grands chimistes français qui ont laissé leur nom dans l'histoire. C'est en effet le seul qui figure dans tous les ouvrages de chimie organique, du plus simple au plus complexe, pour avoir mis au point les organomagnésiens, une classe de molécules particulièrement utilisées en synthèse organique. Sa vie En 1894, il prépare une licence de sciences-physiques à la faculté des sciences de Lyon. Il obtient un modeste poste de préparateur dans le laboratoire de chimie de Philippe Barbier, personnage imposant et autoritaire. Barbier était un des précurseur à utiliser les organométalliques comme composés particulièrements réactifs, tels les organozinciques voire les organomagnésiens. C'est dans ce laboratoire que Grignard va mettre au point les organomagnésiens. Il publiera d'ailleurs en 1900, un article dans les comptes rendus de l'académie des sciences : " Sur quelques nouvelles combinaisons organométalliques du magnésium et leur application à la synthèse d'alcools et d'hydrocarbures ". On dénombrera en 1906 près de 350 publications faisant référence aux réactifs de Grignard, et près de 700 en 1910, ce qui reste important encore aujourd'hui mais qui était énorme pour l'époque. En 1901, il présente une thèse remarquée sur les organomixtes. Il travaille un temps à la faculté des sciences de Besançon mais reviendra à Lyon comme maître de conférence.
Nobel Prizes In Chemistry nobel Prizes in Chemistry. This Year's nobel Prize in Chemistry. Chemistry1901. grignard, victor, France, Nancy University, * 1871, + 1935 http://chemserv.bc.edu/sites/Nobel.html
Extractions: Nobel Prizes in Chemistry This Year's Nobel Prize in Chemistry VAN'T HOFF, JACOBUS HENRICUS, the Netherlands, Berlin University, Germany, * 1852, + 1911: "in recognition of the extraordinary services he has rendered by the discovery of the laws of chemical dynamics and osmotic pressure in solutions". FISCHER, HERMANN EMIL, Germany, Berlin University, * 1852, + 1919 "in recognition of the extraordinary services he has rendered by his work on sugar and purine syntheses". ARRHENIUS, SVANTE AUGUST, Sweden, Stockholm University, * 1859, + 1927 "in recognition of the extraordinary services he has rendered to the advancement of chemistry by his electrolytic theory of dissociation". RAMSAY, Sir WILLIAM, Great Britain, London University, * 1852, + 1916: "in recognition of his services in the discovery of the inert gaseous elements in air, and his determination of their place in the periodic system". VON BAEYER, JOHANN FRIEDRICH WILHELM ADOLF, Germany, Munich University, * 1835, + 1917: "in recognition of his services in the advancement of organic chemistry and the chemical industry, through his work on organic dyes and hydroaromatic compounds".
Grignard, Victor grignard, victor 18711935, French chemist. He shared the 1912 nobel Prize in Chemistryfor his work in organic synthesis based on his discovery (1900) of the http://www.slider.com/enc/22000/Grignard_Victor.htm