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REFERENCE ENCYCLOPAEDIA Hutchinson's
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HUTCHINSON ENCYCLOPEDIA Pauling, Linus Carl US theoretical chemist and biologist. He was awarded the Nobel Prize for Chemistry in 1954 for his study of the nature of chemical bonds, especially in complex substances. His ideas are fundamental to modern theories of molecular structure. He also investigated the properties and uses of vitamin C as related to human health. He was awarded the Nobel Prize for Peace in 1962 for having campaigned for the control of nuclear weapons and nuclear testing. Work
Pauling's work on the nature of the chemical bond included much new information about interatomic distances. Applying his knowledge of molecular structure to proteins in blood, he discovered that many proteins have structures held together with hydrogen bonds, giving them helical shapes. He was a pioneer in the application of quantum-mechanical principles to the structures of molecules, relating them to interatomic distances and bond angles by X-ray and electron diffraction, magnetic effects, and thermochemical techniques. In 1928, Pauling introduced the concept of hybridization of bonds. This provided a clear, basic insight into the framework structure of all carbon compounds in effect, of the whole of organic chemistry. He also studied electronegativity of atoms and polarization (location of electrons) in chemical bonds. Electronegativity values can be used to show why certain substances, such as hydrochloric acid, are acid, whereas others, such as sodium hydroxide, are alkaline. Much of this work was consolidated in his book | |
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